|
|
octanoyl-CoA + acetyl-CoA <=> 3-oxodecanoyl-CoA + CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
|
BRENDA:
BS189546
KEGG:
R03778
MetaCyc:
RXN-13617
SABIO-RK:
3537
|
|
|
|
3-cis-dodecenoyl-CoA <=> trans-2-dodecenoyl-CoA
|
5.3.3.8
Delta3-Delta2-enoyl-CoA isomerase
|
–
|
|
BRENDA:
BS1114
KEGG:
R04100
MetaCyc:
RXN-7931
|
|
|
|
2-trans,5-cis-tetradecadienoyl-CoA <=> (3E,5Z)-tetradeca-3,5-dienoyl-CoA
|
5.3.3.8
Delta3-Delta2-enoyl-CoA isomerase
|
–
|
|
MetaCyc:
RXN0-5391
SABIO-RK:
9711
|
|
|
|
(S)-3-hydroxyhexanoyl-CoA + NAD+ <=> 3-oxohexanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
|
BRENDA:
BS188067
KEGG:
R04748
MetaCyc:
RXN-12570
SABIO-RK:
4404
|
|
|
|
(S)-3-hydroxy-(5Z)-tetradecenoyl-CoA + NAD+ <=> 3-oxo-(5Z)-tetradecenoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
|
MetaCyc:
RXN-14393
|
|
|
|
hexanoyl-CoA + acetyl-CoA <=> 3-oxooctanoyl-CoA + CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
|
BRENDA:
BS189545
KEGG:
R04747
MetaCyc:
RXN-14277
SABIO-RK:
4403
|
|
|
|
(S)-3-hydroxydecanoyl-CoA <=> trans-2-decenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
|
BRENDA:
BS2103
KEGG:
R04744
MetaCyc:
RXN-13616
SABIO-RK:
4400
|
|
|
|
L-3-hydroxydodecanoyl-CoA <=> trans-2-dodecenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
|
BRENDA:
BS2104
KEGG:
R04170
MetaCyc:
RXN-20675
SABIO-RK:
3890
|
|
|
|
decanoyl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> trans-2-decenoyl-CoA + reduced_flavodoxin
|
1.3.8.7
medium-chain acyl-CoA dehydrogenase
|
–
|
|
MetaCyc:
RXN-13615
|
|
|
|
3-oxo-(7Z)-hexadecenoyl-CoA + NADH + H+ <=> (S)-3-hydroxy-(7Z)-hexadecenoyl-CoA + NAD+
|
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
|
|
MetaCyc:
RXN-17781
|
|
|
|
(S)-3-hydroxy-(9Z)-octadecenoyl-CoA <=> 2-trans-9-trans-octadecendienoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
|
–
|
|
MetaCyc:
RXN-17776
|
|
|
|
NAD+ + (S)-3-hydroxy-(9Z)-octadecenoyl-CoA <=> NADH + H+ + 3-oxo-(9Z)-octadecenoyl-CoA
|
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
|
|
MetaCyc:
RXN-17777
|
|
|
|
butyryl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> crotonyl-CoA + reduced_flavodoxin
|
1.3.8.1
short-chain acyl-CoA dehydrogenase
|
–
|
|
MetaCyc:
BUTYRYL-COA-DEHYDROGENASE-RXN
|
|
|
|
(S)-3-hydroxyoctanoyl-CoA + NAD+ <=> 3-oxooctanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
|
BRENDA:
BS188060
KEGG:
R04745
MetaCyc:
RXN-20679
SABIO-RK:
4401
|
|
|
|
oleic_acid + CoA + ATP <=> oleoyl-CoA + AMP + diphosphate
|
1.13.12.7
firefly luciferase
6.2.1.12
4-coumarate---CoA ligase
6.2.1.3
long-chain-fatty-acid---CoA ligase
6.2.1.B3
|
–
–
–
–
|
|
BRENDA:
BS279
MetaCyc:
RXN-9644;
RXN0-7239
SABIO-RK:
10317
|
|
|
|
(S)-3-hydroxydecanoyl-CoA + NAD+ <=> 3-oxodecanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
|
BRENDA:
BS188068
KEGG:
R04743
MetaCyc:
RXN-12490
SABIO-RK:
4399
|
|
|
|
oleoyl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> 2-trans-9-trans-octadecendienoyl-CoA + reduced_flavodoxin
|
1.3.8.8
long-chain acyl-CoA dehydrogenase
|
–
|
|
MetaCyc:
RXN-17775
|
|
|
|
octanoyl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> 2-octenoyl-CoA + reduced_flavodoxin
|
1.3.8.7
medium-chain acyl-CoA dehydrogenase
|
–
|
|
MetaCyc:
RXN-14229
|
|
|
|
(S)-3-hydroxybutyryl-CoA <=> H2O + crotonyl-CoA
|
1.3.8.7
medium-chain acyl-CoA dehydrogenase
4.2.1.116
3-hydroxypropionyl-CoA dehydratase
4.2.1.150
short-chain-enoyl-CoA hydratase
4.2.1.17
enoyl-CoA hydratase
|
–
–
–
–
|
|
BRENDA:
BR51003
KEGG:
R03026
MetaCyc:
RXN-11667;
RXN-15014
SABIO-RK:
2876
|
|
|
|
hexanoyl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> trans-2-hexenoyl-CoA + reduced_flavodoxin
|
1.3.8.7
medium-chain acyl-CoA dehydrogenase
|
–
|
|
MetaCyc:
RXN-14278
|
|
|
|
(3E,5Z)-tetradeca-3,5-dienoyl-CoA + H2O <=> H+ + (3E,5Z)-tetradecadienoate + CoA
|
3.1.2
|
–
|
|
MetaCyc:
RXN0-5390
|
|
|
|
(S)-3-hydroxyhexanoyl-CoA <=> trans-2-hexenoyl-CoA + H2O
|
4.2.1.150
short-chain-enoyl-CoA hydratase
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
–
|
|
BRENDA:
BS2101
KEGG:
R04749
MetaCyc:
RXN-12567;
RXN-20677
SABIO-RK:
4405
|
|
|
|
(7Z)-hexadecenoyl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> (2E,7Z)-hexadecenoyl-CoA + reduced_flavodoxin
|
1.3.8.8
long-chain acyl-CoA dehydrogenase
|
–
|
|
MetaCyc:
RXN-17779
|
|
|
|
(S)-3-hydroxybutyryl-CoA + NAD+ <=> acetoacetyl-CoA + NADH + H+
|
1.1.1.178
3-hydroxy-2-methylbutyryl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
1.1.1.36
acetoacetyl-CoA reductase
|
–
–
–
|
|
BRENDA:
BS188053
KEGG:
R01975
MetaCyc:
RXN-11662
SABIO-RK:
2018
|
|
|
|
L-3-hydroxydodecanoyl-CoA + NAD+ <=> 3-oxododecanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
|
KEGG:
R04741
MetaCyc:
RXN-20676
|
|
|
|
(S)-3-hydroxy-(7Z)-hexadecenoyl-CoA <=> (2E,7Z)-hexadecenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
|
–
|
|
MetaCyc:
RXN-17780
|
|
|
|
(7Z)-hexadecenoyl-CoA + acetyl-CoA <=> 3-oxo-(9Z)-octadecenoyl-CoA + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
|
|
MetaCyc:
RXN-17778
|
|
|
|
acetyl-CoA <=> acetoacetyl-CoA + CoA
|
1.1.1.34
hydroxymethylglutaryl-CoA reductase (NADPH)
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
2.3.1.38
[acyl-carrier-protein] S-acetyltransferase
2.3.1.9
acetyl-CoA C-acetyltransferase
|
–
–
–
–
–
|
|
BRENDA:
BR44092
KEGG:
R00238
MetaCyc:
ACETYL-COA-ACETYLTRANSFER-RXN
SABIO-RK:
531
|
|
|
|
butyryl-CoA + acetyl-CoA <=> 3-oxohexanoyl-CoA + CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
2.3.1.9
acetyl-CoA C-acetyltransferase
|
–
–
–
|
|
BRENDA:
BS189544
KEGG:
R01177
MetaCyc:
RXN-12565
SABIO-RK:
1414
|
|
|
|
(5Z)-tetradecenoyl-CoA + acetyl-CoA <=> 3-oxo-(7Z)-hexadecenoyl-CoA + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
|
|
MetaCyc:
RXN-17782
|
|
|
|
(5Z)-tetradecenoyl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> 2-trans,5-cis-tetradecadienoyl-CoA + reduced_flavodoxin
|
1.3.8.8
long-chain acyl-CoA dehydrogenase
|
–
|
|
MetaCyc:
RXN-17783
|
|
|
|
decanoyl-CoA + acetyl-CoA <=> 3-oxododecanoyl-CoA + CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
|
BRENDA:
BS189547
KEGG:
R04742
MetaCyc:
RXN-14274
SABIO-RK:
4398
|
|
|
|
(S)-3-hydroxyoctanoyl-CoA <=> 2-octenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
|
BRENDA:
BS2102
KEGG:
R04746
MetaCyc:
RXN-20678
SABIO-RK:
4402
|
|
|
|
(S)-3-hydroxy-(5Z)-tetradecenoyl-CoA <=> 2-trans,5-cis-tetradecadienoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
|
–
|
|
MetaCyc:
RXN0-5393
|
|
|
|
3-cis-dodecenoyl-CoA + acetyl-CoA <=> 3-oxo-(5Z)-tetradecenoyl-CoA + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
|
|
MetaCyc:
RXN-14394
|
|